@Raymonde22
No. As far as I know, you need to create two separate bookings and keep an eye on the calendars so the property doesn't get double booked.
If you use instant booking, that is more difficult, but what you could try is putting the option that gets the most bookings on IB and the other on request booking only, i.e. turn off IB. So, if you mostly get guests booking for just one bedroom, make that one the listing with IB. Hope that makes sense.