The assumption is that guests will have access to the spaces you have allowed them to use by virtue that they have rented them, at anytime between their check in and check out times.
If you can't live with this arrangement, then you must be very clear in your listing that guests should be out of the house from 10am-5pm, and include it in your house rules as well. This will, no doubt, reduce the desireability of your listing.
The reason I have used the word "must" above is that without clarity, I can guarnatee that you will have some scathing reviews. This AirBNB thing does require that we list our spaces and homes very accurately.